This issue is currently on our list to fix up. For some reason, windows that have been removed from the Primary taskbar (like ones that have been moved to a DF taskbar) don't register in Task View any more. There is a workaround, which is to set the Taskbar Mode on the Settings > Taskbar tab to "Windows taskbar shows all windows..." It's definitely not ideal, but hopefully a decent compromise until we can find a way to fix it up in the future

Unfortunately not, no. Windows still removes apps from Win + Tab and other Task View related functions if they don't have a button on the Windows taskbar. It's not something we can fix from our side currently.